Insertion Polymerization of Acrylate
نویسندگان
چکیده
منابع مشابه
Insertion polymerization of acrylate.
Multiple insertions of acrylate in copolymerization with ethylene, and an insertion homo-oligomerization of methyl acrylate were observed for the first time. Key to these findings, and to mechanistic insights reported, are labile-substituted complexes as catalyst precursors.
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Diazaphospholidine-sulfonato Pd(II) complexes [{.r-P,O-(N-Ar!C214N!P)C6H4S03}PdMe(L)] l-L (L::: dmso, pyridine, hltidine, or Jl-LiCI(solvent)j la: Ar = Ph, Ib: Ar = 2-MeC614, lc: Ar = 2-MeOC6H", Id: Ar ::: 2,4,6-Me3C6H!J le: Ar = 2,6-iPr2C6H3' If: Ar = 2,6-(p-tolyl)2C6H3) were prepared and structurally characterized. The regioselectivity of methyl acrylate (MA) insertion into the Pd-Me bond is ...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2008
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja808017n